Novel Isatin-Schiff Base Cu (II) and Ni(II) Complexes. X-ray Crystal Structure of Bis[3-(4-hexylphenylimino)-1H-indol-2(3H)-one]-dichlorocopper(II) Complex |
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作者姓名: | Ayse ERCAG Sema Oztürk YILDIRIM Mehmet AKKURT Mahmure Ustün OZGUR Frank W. HEINEMANN |
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作者单位: | Istanbul University Engineering Faculty Chemistry Department Avcilar Istanbul Turkey 34320,Department of Physics Faculty of Arts and Sciences Erciyes University Kayseri Turkey 38039,Department of Physics Faculty of Arts and Sciences Erciyes University Kayseri Turkey 38039,Yildiz Technical University Faculty of Arts and Sciences Chemistry Department Davutpasa Istanbul Turkey 34210,Institut für Inorganische Chemie UniversittErlangen-Nürnberg Egerlandstrasse 1 D-91058 Erlangen Germany |
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摘 要: | Schiff bases of isatin were reported to possess antibacterial, antifungal, antiviral, anti-HIV, antiprotozoal, and anthelmintic activities1. They also exhibit significantanticonvulsant activity, apart from other pharmacological properties2. Conductingsubs…
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Novel Isatin-Schiff Base Cu (II) and Ni(II) Complexes. X-ray Crystal Structure of Bis[3-(4-hexylphenylimino)-1H-indol-2(3H)-one]-dichlorocopper(II) Complex |
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Abstract: | Schiff base ligand (HL) derived from 4-hexylaniline with isatin (1H-indole-2,3-dione)and its complexes with Cu(II), Ni(II) were prepared and characterized by analytical, spectroscopic(IR, UV-Vis, Mass) techniques, electrical conductivity, magnetic and thermal measurements. Thecrystal and molecular structure of Cu(HL)2Cl2] was determined by a single-crystal X-raydiffraction study. The molecular structure of the title compound has an inversion center on theCu atom. |
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Keywords: | Mononuclear Cu(II) and Ni(II) complexes isatin-anilines Schiff base crystal structure |
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