Rearrangement of 2-methyl-2,3-epoxypentane: a kinetic study |
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Authors: | Kurti Kurtev Darina Kehayova Magdalena Mitkova and Atanas Tomov |
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Institution: | (1) Department of Organic Synthesis 1, Prof. Yakimov Str., Zlatarov University, 8010 Bourgas, Bulgaria |
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Abstract: | The kinetics of the rearrangement of 2-methyl-2,3-epoxypentane over ZnCl2/pumice stone is reported. 2-Methyl-3-pentanone and 2,2-dimethylbutanal are formed in parallel reactions. The reaction scheme
and kinetic equations best fitting the experimental data are given.
This revised version was published online in August 2006 with corrections to the Cover Date. |
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Keywords: | 3-epoxypentane ZnCl2/pumice stone kinetics 2-Methyl-2 epoxides rearrangement |
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