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Rearrangement of 2-methyl-2,3-epoxypentane: a kinetic study
Authors:Kurti Kurtev  Darina Kehayova  Magdalena Mitkova and Atanas Tomov
Institution:(1) Department of Organic Synthesis 1, Prof. Yakimov Str., Zlatarov University, 8010 Bourgas, Bulgaria
Abstract:The kinetics of the rearrangement of 2-methyl-2,3-epoxypentane over ZnCl2/pumice stone is reported. 2-Methyl-3-pentanone and 2,2-dimethylbutanal are formed in parallel reactions. The reaction scheme and kinetic equations best fitting the experimental data are given. This revised version was published online in August 2006 with corrections to the Cover Date.
Keywords:3-epoxypentane  ZnCl2/pumice stone  kinetics  2-Methyl-2  epoxides rearrangement
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