Synthetic, spectral and solution studies on imidazolate-bridged copper(II)-copper(II) and copper(II)-zinc(II) complexes |
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| Authors: | Subodh Kumar R N Patel P V Khadikar and K B PAndeya |
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| Institution: | (1) Department of Chemistry, APS University, 486 003 Rewa, India;(2) CSJM University, 208 016 Kanpur, India |
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| Abstract: | Synthesis, spectral and solution studies on 2-ethyl imidazolate-bridged (2-EtIm) homo-binuclear copper(II)-copper(II) and
hetero-binuclear copper(II)-zinc(II) homologue are described. Magnetic moment values of homo-binuclear complexes indicate
that the imidazolate group can mediate antiferromagnetic interactions. Optical spectra of hetero-binuclear complex at varying
pH values suggest that the imidazolate-bridged complex is stable over the pH-range 7.15–10.0. |
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| Keywords: | 2-Ethylimidazolate-bridged homo/hetero-binuclear complexes anti-ferromagnetic interactions |
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