Fast peroxyoxalate chemiluminescence for minimized analytical separation systems |
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| Authors: | Lee Ji Hoon Je Jongtae Schlautmana Mark A Carraway Elizabeth R |
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| Affiliation: | Department of Environmental Toxicology and the Clemson Institute of Environmental Toxicology, Clemson University, Pendleton, SC 29670, USA. lee@clemson.edu |
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| Abstract: | The maximum intensity, Imax, and time required to reach the maximum emission, taumax, for 1-aminopyrene monitored in 1,1'-oxalyldi-4-methylimidazole (OD4MI) chemiluminescence (CL) reactions are approximately 61 times higher and 16 times faster than their respective values for bis(2,4,6-trichlorophenyl)oxalate (TCPO) CL reactions in the presence of imidazole (ImH). |
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