Determination of the spin-spin centrifugal distortion parameters for deuterated selenoformaldehyde in its first excited triplet state |
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| Authors: | Christian Hill |
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| Institution: | The Physical and Theoretical Chemistry Laboratory, Department of Chemistry, Oxford University, South Parks Road, Oxford OX1 3QZ, England, UK |
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| Abstract: | Recently-formulated centrifugal distortion corrections to the spin-spin Hamiltonian have been used to analyse the first excited triplet state (ã3A2) of deuterated selenoformaldehyde. By including six spin-spin centrifugal distortion parameters, it is possible to account for the energy levels of this state using a single set of three rotational constants, A, B, and C, where previously nine spin-dependent parameters were required. |
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