| 碳载CuTAPP的ESR研究(Ⅰ) |
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| 引用本文： | 刘小平,陆君涛,查全性.碳载CuTAPP的ESR研究(Ⅰ)[J].物理化学学报,1988,4(5):483-488. |
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| 作者姓名： | 刘小平 陆君涛 查全性 |
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| 作者单位： | Department of Chemistry; Wuhan University; Wuhan |
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| 摘 要： | 本文给出了碳载CuTAPPCopper tetra-(p-trimethylammoniumphenyl)porphine iodide]的磁共振参数及由此得到的若干键参数和配体场跃迁能, 所得结果与文献中未碳载的铜卟啉和铜酞菁进行了比较。
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| 收稿时间： | 1986-12-23 |
| 修稿时间： | 1987-08-31 |
ESR STUDIES OF CuTAPP SUPPORTED ON ACTIVE CARBON (Ⅰ) |
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| Liu Xiaoping,Lu Juntao,Cha Chuansin.ESR STUDIES OF CuTAPP SUPPORTED ON ACTIVE CARBON (Ⅰ)[J].Acta Physico-Chimica Sinica,1988,4(5):483-488. |
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| Authors: | Liu Xiaoping Lu Juntao Cha Chuansin |
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| Institution: | Department of Chemistry; Wuhan University; Wuhan |
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| Abstract: | Well resolved ESR spectra of CuTAPP Copper tetra-(p-trimethylammoniumphenyl) porphine iodide] supported on active carbon was obtained by proper dilution of CuTAPP on the substrate. The hyperfine lines of copper, super-hyperfine lines of the four nitrogen atoms and anomalous lines appeared on the spectrum. Computer simulated spectrum of CuTAPP was found to be in good accordance with the experimental one. The ESR spectrum of CuTAPP supported on active carbon was discussed in detail to yield the ESR and derived parameters, which are found to be close to those of non-supported copper porphins and phthalocyanins. |
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