Kinetic and thermodynamic parameters of 99Mo sorption on thermally treated hydrotalcite |
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Authors: | F Granados Correa J Serrano Gómez |
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Institution: | (1) Instituto Nacional de Investigaciones Nucleares, A. P. 18-1027, Col. Escandón, Delegación Miguel Hidalgo, C. P. 11801, México, D. F., México;(2) Instituto Nacional de Investigaciones Nucleares, A. P. 18-1027, Col. Escandón, Delegación Miguel Hidalgo, C. P. 11801, México, D. F., México |
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Abstract: | Summary Thermally treated hydrotalcite was synthesized and its ability to sorb 99Mo from aqueous solutions was studied under static conditions as a function of initial concentration, amount of sorbent and
pH. X-ray diffraction was used to characterize synthesized calcined hydrotalcite. The values of sorption data were fitted
to Freundlich, Langmuir and Dubinin-Radushkevich (D-R) sorption isotherms. The mean energy of sorption was calculated as 5.24
kJ. mol-1from D-R sorption isotherm. The Lagergren equation has been used for the study of the kinetic process. The rate constants
of 99Mo sorption on calcined hydrotalcite were calculated at various temperatures (293-323 K). The thermodynamic constans have
been calculated and the standard enthalpy of the system was found to be<span style='font-size:12.0pt; font-family:Symbol;mso-bidi-font-family:Symbol'>DH°=11.5±0.3 kJ. mol-1. The values of calculated<span style='font-size:12.0pt;font-family:Symbol;mso-bidi-font-family: Symbol'>DG° and<span style='font-size:12.0pt;font-family: Symbol;mso-bidi-font-family:Symbol'>DS° were</o:p>-13.9±2.0 kJ. mol-1and (8.7±0.2). 10-2kJ. K-1. mol-1, respectively. These results show that the sorption process is endothermic, spontaneous in nature and the degree of freedom
of ions is increased by sorption. |
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