New type dithiolene complex based on 4,5-(1,4-dioxane-2,3-diyldithio)-1,3-dithiol ligand: Synthesis,experimental and theoretical investigation |
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| Authors: | G. Soras N. Psaroudakis M.J. Manos A.J. Tasiopoulos D.G. Liakos G.A. Mousdis |
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| Affiliation: | 1. Theoretical and Physical Chemistry Institute, National Hellenic Research Foundation, 48 Vass. Constantinou Aven., 116 35 Athens, Greece;2. University of Athens Chemistry Department, University Campus, Athens, GR 157-71, Greece;3. Department of Chemistry, University of Cyprus, 1678 Nicosia, Cyprus;4. Institute for Physical and Theoretical Chemistry, Bonn University, Wegelerstrasse 12, 53115 Bonn, Germany |
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| Abstract: | ![]()
A new Nickel complex with an extended multisulfur dithiolene ligand Ni(edodddt)2 (edodddt = 2,3,4α,8α-tetrahydro-dithiine [2,3-b] [1,4] dioxo-6,7-dithiolene) has been synthesized and characterized by electrochemical measurements, IR, UV–Vis and NMR spectroscopy. Its crystal structure was resolved by X-ray diffraction on a single crystal. DFT calculations were made in order to compare the results with the experimental findings and gain an insight of the properties of this new dithiolene complex. |
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| Keywords: | Dithiolene complexes IR and Raman spectra Ab initio calculations Crystal structure Cyclic voltammetry |
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