Synthesis and Characterization of Poly(ether ether ketone)s with (2,5‐dihydroxy)phenyl Side Group |
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Authors: | Xigui Yue Yaming Niu Shaowei Guan Aize Li Haibo Zhang |
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Institution: | Alan G. MacDiarmid Institute, College of Chemistry, Jilin University , Chang Chun, P. R., China |
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Abstract: | A new monomer, (2,5‐dimethoxy)phenylhydroquinone (DMPH), was prepared in a two‐step synthetic procedure. One aromatic poly(ether ether ketone)s with 2,5‐dimethoxy phenyl side group (DMP‐PEEK) was synthesized via an aromatic nucleophilic substitution reaction with 4,4′‐difluorobenzophenone (DFB). Poly(ether ether ketone)s with 2,5‐dihydroxy phenyl side group (DHP‐PEEK) was obtained via hydrolysis of methoxy group on the DMP‐PEEK. Both of the high molecular weight polymers could be obtained despite the steric effect of the bulky pendant groups. The two polymers have good solubility at room temperature. |
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Keywords: | aromatic poly(ether ether ketone)s hydroxyl adhesion property functional polymers |
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