Structural and Magnetic Properties of FexTiSe2 Intercalation Compounds

Abstract

Magnetic and neutron studies are done about iron-intercalated titanium diselenide, Fe^xTiSe² with 0<x≤0.5. A neutron diffraction measurement shows that Fe-atoms are located between neighboring selenium layers. Magnetic measurements show that FexTiSe² are spin glasses for 0. 15≤^x≤0.22 and antiferromagnets for 0.25≤^x≤0.5. T-x magnetic phase diagram is determined. This diagram is slightly different from that determined by Huntley et al. The difference may be caused by a formation of Fe-clusters in their samples. The x-dependence of the parameters of paramagnetic susceptibilities is determined.