The Influence of Pore Structures and Degree of Crosslinking on Catalytic Properties of Aminomethyl Polystyrene Resins Supported Dendritic Sn Complexes |
| |
| Authors: | Jiaqin Wang Renren Wang Zhe Zhang Cuilin Li Zhiwang Yang |
| |
| Institution: | Key Laboratory of Polymer Materials of Gansu Province, College of Chemistry and Chemical Engineering , Northwest Normal University , Lanzhou, China |
| |
| Abstract: | Seven different aminomethyl polystyrene resins supported dendritic Sn complexes were prepared by solid phase synthesis methodology. All the synthesized complexes show promising catalytic activities for the Baeyer‐Villiger oxidation of ketones with hydrogen peroxide and affording the corresponding lactones or esters. The influence of different pore structures and the degree of crosslinking of the aminomethyl polystyrene resins on catalytic properties of the supported dendritic Sn complexes were well discussed. |
| |
| Keywords: | aminomethyl polystyrene dendrimer catalytic Baeyer‐Villiger oxidation pore structure degree of crosslinking |
|
