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Mössbauer Spectra of FePS3-Cobaltocene Intercalation Compound
Authors:Hiroshi Sakai  Takashi Yamazaki  Nobuya Machida  Toshihiko Shigematsu  Saburo Nasu
Institution:1. Department of Chemistry, Faculty of Science , Konan University , Okamoto 8-9-1, Higashinada, Kobe , 658-8501 , Japan;2. Department of Material Physics, Faculty of Engineering Science , Osaka University , Machikaneyama 1-3, Toyonaka , 560-8531 , Japan
Abstract:Abstract

Mössbauer spectra of the FePS3-cobaltocene intercalation compound were measured in the temperature range of 300K to 10K. The spectra, distinct from those of pure FePS3, suggest the charge transfer from cobaltocene to Fe-S antibonding orbitals of the FePS3 host lattice.
Keywords:Mössbauer spectra  intercalation  layered compound  FePS3  charge transfer
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