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Swelling Characterization of the Superabsorbent Copolymer in the Petroleum-Based Solvent-Water Mixtures
Authors:Osman ?smail  Berceste Beyribey
Institution:1. Y?ld?z Technical University, Davutpasa Campus, Faculty of Chemical &2. Metallurgical Engineering, Chemical Engineering Department , Esenler , Istanbul , Turkey
Abstract:The crosslinked and porous copolymer grains were synthesized by inverse suspension polymerization of acrylamide. The synthesized copolymer was characterized by Fourier Transform Infrared Spectroscopy (FTIR) and Scanning Electron Microscopy (SEM). It was achieved to absorbed 418 g water by 1 g copolymer after 5 min waiting time. Moreover, it was seen that about 99% of water was absorbed by 1 g copolymer in the solvent water mixtures (300 mL solvent–200 mL distilled water) after 2.5 min waiting time. The diffusion coefficients of the copolymer in the solvent-water mixtures were found between 8.87 · 104 and 10.64 · 104 cm2s?1. Furthermore, the copolymer in distilled water achieved to reach a high value of the diffusion coefficient (13.2 · 104 cm2s?1).
Keywords:Swelling  superabsorbent polymer  diffusion  water absorption  solvent-water mixtures
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