| SYNTHESIS AND STRUCTURE OF[Et_4N]_3[FE_3(SPh)_3Br_3Cl_3] |
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| 摘 要： | <正> The title compound was synthesized and its structure solved. The formula is Et4N]3Fe3(SPh)3Br3Cl3]. M=1231.95, monoclinic, space group C2/c, a=24.569(4), b=13.504(2), c=18.348.(3)A, β=110.78(1)°, V=5691(3)A3, Z=4, Dm= 1.41, Dc=1.44-g/cm3. The flat structure of the anion has. a planar Fe3S3] ring and three phenyl groups. Statistical distribution of chlorine and bromine atoms on two sides of the Fe3S3] plane results in a C2 symmetry of the anion.
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SYNTHESIS AND STRUCTURE OF[Et_4N]_3[FE_3(SPh)_3Br_3Cl_3] |
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| Abstract: | The title compound was synthesized and its structure solved. The formula is Et4N]3Fe3(SPh)3Br3Cl3]. M=1231.95, monoclinic, space group C2/c, a=24.569(4), b=13.504(2), c=18.348.(3)A, β=110.78(1)°, V=5691(3)A3, Z=4, Dm= 1.41, Dc=1.44-g/cm3. The flat structure of the anion has. a planar Fe3S3] ring and three phenyl groups. Statistical distribution of chlorine and bromine atoms on two sides of the Fe3S3] plane results in a C2 symmetry of the anion. |
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