| 鼓形有机锡氧簇合物[nBuSn(O)(NNA)]6的合成、晶体结构及生物活性 |
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| 引用本文： | 邓奕芳,陈满生,张春华,邝代治,聂 雪.鼓形有机锡氧簇合物[nBuSn(O)(NNA)]6的合成、晶体结构及生物活性[J].无机化学学报,2009,25(12):2229-2232. |
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| 作者姓名： | 邓奕芳 陈满生 张春华 邝代治 聂 雪 |
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| 作者单位： | 功能金属有机材料湖南省普通高等学校重点实验室,衡阳师范学院化学与材料科学系,衡阳,421008 |
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| 基金项目： | 湖南省重点学科建设项目;湖南省青年骨干教师基金，衡阳师范学院青年骨干教师基金，湖南省科技厅项目，衡阳市科技局资助项 |
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| 摘 要： | The title complex nBuSn(O)(NNA)]6(1), was synthesized by the reaction of nBuSn(O)OH with naphthalene acetic acid in 1∶1 molar radio, where HNNA=naphthalene acetic acid. The complex was characterized by IR, 1H NMR spectra and elemental analysis. The crystal structure was determined by X-ray diffraction method. It crystallizes in monoclinic system with space group P21/n. The crystal data are: a=2.647 1(5) nm, b=1.412 9(3) nm, c=2.805 7(6) nm, β=116.185(3)°, Z=4, V=9.417(3) nm3, Dc=1.595 g·cm-3, μ=1.632 mm-1, F(000)=4 512, R1=0.050 3, wR2=0.131 2. The structure shows a distorted octahedral configuration with six-coordination for the central tin atom. The bioactivity test shows that the Sn(Ⅳ) complex has selective antibacterial property. CCDC: 752497.
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| 关 键 词： | 有机锡簇合物 萘乙酸 晶体结构 抑菌活性 |
Synthesis, Crystal Structure and Biological Activity of Drum Organooxotin Cluster [nBuSn(O)(NNA)]6 |
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| DENG Yi-Fang,CHEN Man-Sheng,ZHANG Chun-Hu,KUANG Dai-Zhi and NIE Xue.Synthesis, Crystal Structure and Biological Activity of Drum Organooxotin Cluster [nBuSn(O)(NNA)]6[J].Chinese Journal of Inorganic Chemistry,2009,25(12):2229-2232. |
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| Authors: | DENG Yi-Fang CHEN Man-Sheng ZHANG Chun-Hu KUANG Dai-Zhi and NIE Xue |
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| Institution: | Key Laboratory of Functional Organometallic Materials of Hengyang Normal University, College of Hunan Province, Department of chemistry and Materials Science, Hengyang, Hunan 421008,Key Laboratory of Functional Organometallic Materials of Hengyang Normal University, College of Hunan Province, Department of chemistry and Materials Science, Hengyang, Hunan 421008,Key Laboratory of Functional Organometallic Materials of Hengyang Normal University, College of Hunan Province, Department of chemistry and Materials Science, Hengyang, Hunan 421008,Key Laboratory of Functional Organometallic Materials of Hengyang Normal University, College of Hunan Province, Department of chemistry and Materials Science, Hengyang, Hunan 421008 and Key Laboratory of Functional Organometallic Materials of Hengyang Normal University, College of Hunan Province, Department of chemistry and Materials Science, Hengyang, Hunan 421008 |
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| Abstract: | The title complex~nBuSn(O)(NNA)]_6(1),was synthesized by the reaction of~nBuSn(O)OH with naphthalene acetic acid in 1:1 molar radio,where HNNA=naphthalene acetic acid.The complex was characterized by IR,~1H NMR spectra and elemental analysis.The crystal structure Was determined by X-ray diffraction method.It crystallizes in monoclinic system with space group P2_1/n.The crystal data are:a=2.6471(5)nm,b=1.4129(3)nm,c=2.805 7(6)nm,β=116.185(3)°,Z=4,V=9.417(3)nm~3,D_c=1.595g·cm~(-3),μ=1.632mm~(-1),F(000)=4512,R_1=0.0503,wR_2=0.1312.The structure shows a distorted octahedral configuration with six-coordination for the central tin atom.The bioactivity test shows that the Sn(Ⅳ)complex has selective antibacterial property.CCDC:752497. |
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| Keywords: | organooxotin cluster naphthalene acetic acid crystal structure antibacterial activity |
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