La0.67Ca0.33MnO3薄膜中的矫顽力随膜厚与衬底的变化

系统研究了衬底为SrTiO3和LaAlO3上的La0.67Ca0.33MnO3薄膜中的矫顽力随厚度和应变的变化。结构分析表明薄膜为（001）方向织构，而且薄膜中的晶粒尺寸随着薄膜厚度的减小而减小。磁测量表明矫顽力先随着膜厚的减小而增加，在t=10-25nm附近到达一极大值。随后，矫顽力随厚度的减小而降低。还得出矫顽力的大小与测量方向有关：t≥25nm (t≤10nm)时，难磁化方向的矫顽力大于（小于）易磁化方向的矫顽力。据此，我们提出：在厚膜（t≥25nm）中，矫顽力变化由畴壁钉扎机制决定；在超薄膜（t≤10nm）中，则与磁畴的形核机制有关。根据t= 5、10、25、400nm的LCMO/STO薄膜的初始磁化曲线，以及t=5，50nm的LCMO/LAO薄膜的小磁滞回线的测量，我们对薄膜中矫顽力机制作了验证，并且还讨论了钉扎和形核机制发生的非均匀区的尺寸。

Dependence of the coercivity of La0.67Ca0.33MnO3 films on substrate and thickness

We investigate the effects of strain and film thickness on the coercivity of La_0.67Ca_0.33MnO₃ films grown on SrTiO₃ and LaAlO₃ substrates. Textured microstructure with the grain 001] pseudo-cubic axis normal to the film surface is obtained. The average grain size decreases with decreasing film thickness t. The magnetic anisotropy depends upon the substrate-induced strain. Firstly, the intrinsic coercivity _iH_C increases as t varies from 5 nm to 10 nm, then attains a maximum at t～10—25nm. A further increase in t yields a gradual reduction of _iH_C. By the analysis of the dependence of _iH_C on the measured direction of magnetic field, the coercivity mechanism is assumed to be mainly determined by the nucleation of reversed domain and the domain wall pining for t≤10nm and t≥25nm, respectively, which were further verified by the investigation of the initial magnetization curves for the LCMO/STO films with t=5, 10, 25 and 400nm, and the minor magnetic loops for the LCMO/LAO films with t=5 and 50nm. Moreover, the size of the inhomogeneous region in which the nucleation or pinning takes place is discussed.