Unexpected synthesis of a naphthylsilole |
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| Authors: | Vitaliy I Timokhin Ilia A Guzei Robert West |
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| Institution: | (1) Organosilicon Research Center, University of Wisconsin-Madison, 1101 University Ave., Madison, WI 53706, USA |
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| Abstract: | The reaction of 1,4-dilithiotetraphenylbutadiene (2) with 1,1′-dichloro-2,3,4,5-tetraphenyl-1-silole (3) leads to 2,3,4,5-tetraphenyl-1-(1,2,3-triphenylnaphthalen-4-yl)-1H-silole (5) instead of the expected octaphenyl-1,1′-spirobisilole (1). The reaction of 2 with SiC14 in dioxane produced 1 in low yield, confirming results reported earlier. |
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| Keywords: | siloles spirosilicon compounds radical coupling |
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