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磁电CoFe2O4/BaTiO3纳米管的溶胶-凝胶模板法合成和表征
引用本文:华正和,李东,付浩.磁电CoFe2O4/BaTiO3纳米管的溶胶-凝胶模板法合成和表征[J].物理化学学报,2009,25(1):145-149.
作者姓名:华正和  李东  付浩
作者单位:Department of Physics, Huaiyin Teachers College, Huaian 223001, Jiangsu Province, P. R. China; Department of Bioengineering and Chemical Engineering, Huaiyin Institute of Technology, Huaian 223001, Jiangsu Province, P. R. China
摘    要:用溶胶-凝胶模板法合成了CoFe2O4/BaTiO3(CFO/BTO)复合纳米管, 管的直径约为100、200和300 nm, 其长度约为100 μm. X射线衍射(XRD)和选区电子衍射(SAED)都显示复合纳米管中同时存在尖晶石相的CoFe2O4 (CFO)和钙钛矿相的BaTiO3(BTO), 进一步的透射电子显微镜(TEM)研究证实合成的纳米复合物具有明显的管状结构. 磁、电研究表明, 该复合纳米管的磁性与纯CFO纳米管的磁性相当; 而铁电性与纯BTO纳米管的铁电性相当.

关 键 词:溶胶-凝胶模板法  复合纳米管  磁性  铁电性  
收稿时间:2008-07-14
修稿时间:2008-09-17

Sol-Gel Template Synthesis and Characterization of Magnetoelectric CoFe2O4/BaTiO3 Nanotubes
HUA Zheng-He,LI Dong,FU Hao.Sol-Gel Template Synthesis and Characterization of Magnetoelectric CoFe2O4/BaTiO3 Nanotubes[J].Acta Physico-Chimica Sinica,2009,25(1):145-149.
Authors:HUA Zheng-He  LI Dong  FU Hao
Institution:Department of Physics, Huaiyin Teachers College, Huaian 223001, Jiangsu Province, P. R. China; Department of Bioengineering and Chemical Engineering, Huaiyin Institute of Technology, Huaian 223001, Jiangsu Province, P. R. China
Abstract:Magnetoelectric CoFe2O4/BaTiO3 composite nanotubes with lengths of about 100 μm and diameters of about 100, 200, and 300 nmwere prepared by a sol-gel template method. The coexistence of spinel CoFe2O4 (CFO) and perovskite BaTiO3 (BTO) phases in the composite (CFO/BTO) nanotubes was revealed by X-ray diffraction (XRD) and selected area electron diffraction (SAED) patterns. Transmission electron microscopy (TEM) confirmed that the nanocomposite had a tubular microstructure. Magnetic properties of the CFO/BTO composite nanotubes were similar to the properties of pure CFO nanotubes. The ferroelectric properties of the composite nanotubes were equivalent to the ferroelectric properties of pure BTO nanotubes.
Keywords:Sol-gel template method  Composite nanotube  Magnetic property  Ferroelectricity
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