Selective detection of the tolyl cation among other [C7H7]+ isomers by ion/molecule reaction with dimethyl ether |
| |
Authors: | Timothy G Heath John Allison J Throck Watson |
| |
Institution: | 1. Department of Biochemistry, Biochemistry Building, Michigan State University, 48824, East Lansing, MI
|
| |
Abstract: | The ion/molecule reaction of the tolyl cation with dimethyl ether has been investigated using triple quadrupole mass spectrometry. Three isomers with C7H7]+ composition, the 3-tolyl, benzyl, and tropylium cations, were individually selected and reacted with dimethyl ether at a pressure of 1 mtorr in the second quadrupole (Q2) collision cell. Only the tolyl ion reacted to yield a methoxylated product ion peak at m/z 122. This reaction product having m/z 122 is postulated to be identical in structure with the molecular ion of 3-methyl anisole, as supported by thermochemical data and the similarity of the collision induced dissociation (CID) daughter ion mass spectra of the product ion and the molecular ion of authentic 3-methyl anisole. The daughter ion mass spectra of the three C7H7]+ isomers during CID, by using a triple quadrupole mass spectrometer, are nearly identical; on the other hand, the analytical approach based on the ion/molecule reaction with dimethyl ether clearly exhibits distinct gas-phase chemistry reflecting structural differences among the isomers. Sot |
| |
Keywords: | |
本文献已被 SpringerLink 等数据库收录! |
|