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水溶性染料在PbTiO3体系中的光催化降解
引用本文:王俊珍,古凤才,颜秀茹,王建苹,曾淑兰.水溶性染料在PbTiO3体系中的光催化降解[J].应用化学,1995,0(6):29-32.
作者姓名:王俊珍  古凤才  颜秀茹  王建苹  曾淑兰
作者单位:天津大学化学系, 天津 300072
基金项目:国家自然科学基金及天津市21世纪青年科学基金资助项目
摘    要:以PbTiO3为光催化剂,对多种水溶性染料的光催化降解反应进行了研究,结果表明:光降解脱色效率与染料溶液的pH值、光照时间、光源种类及催化剂用量等因素有关.染料溶液浓度为10mg/L,pH=6,催化剂用量为100mg/50mL,直接以太阳光作光源,光照1h以后,脱色率达90%以上,有机染料中硫和氮元素转化为SO42-和NO3-的生成率分别为85%和65%.

关 键 词:水溶性染料  光催化降解  PbTiO3  能带隙  
收稿时间:1995-02-06
修稿时间:1995-07-22

Photodegtgradation of Water-Soluble Dyes in PbTiO_3 System
Wang Junzhen, Gu Fengcai, Yan Xiuru, Wang Jianping, Zeng Shulan.Photodegtgradation of Water-Soluble Dyes in PbTiO_3 System[J].Chinese Journal of Applied Chemistry,1995,0(6):29-32.
Authors:Wang Junzhen  Gu Fengcai  Yan Xiuru  Wang Jianping  Zeng Shulan
Institution:Department of Chemistry, Tianjin University, Tianjin 300072
Abstract:The photocatalytic destruction and decolorization of several water-soluble dyesunder natural sun light and 450W high pressure Hg-lamp irradiation in the presence of photo-catalyst PbTiO_3 were studied.The experiments show that the efficiency of decolorization isrelated to the pH value of dye solution,irradiation time,as well as the intensity of irradia-tion. After irradiation with sun light for 1h,the decolorizing efficiency was up to 90% whenthe concentration of dyes was 10mg/L and the amount of catalyst was 100mg in 50mL dyesolution.
Keywords:water-soluble dye  photocatalytic destruction  PbTiO_3  band gap
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