| 联苯聚醚醚酮酮的合成与性能研究 |
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| 引用本文： | 苑晶,张万金.联苯聚醚醚酮酮的合成与性能研究[J].高等学校化学学报,1994,15(5):763-766. |
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| 作者姓名： | 苑晶 张万金 |
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| 作者单位： | 吉林大学化学系 |
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| 基金项目： | 国家863高技术计划项目 |
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| 摘 要： | 用亲核取代路线合成了含亚联苯结构的新型聚醚醚酮酮（联苯ＰＥＥＫＫ），并对其基本性能进行了测定。结果表明，联苯ＰＥＥＫＫ的Ｔｍ比聚醚醚酮（ＰＥＥＫ）高７７℃，其Ｔｇ比ＰＥＥＫ的高４１℃，且保持了良好的力学性能，本文还对联苯ＰＥＥＫＫ的晶体结构进行了初步探讨。
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| 关 键 词： | 聚醚醚酮酮 联苯二酚 双苯 |
The Synthesis and Properties of Polyetheretherketoneketone Containing Biphenyl |
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| YUAN Jng,ZHANG Wan-Jin,NA Hui, JI Xiang-Ling,WANG Jun-Zuo,Wu Zhong-Wen.The Synthesis and Properties of Polyetheretherketoneketone Containing Biphenyl[J].Chemical Research In Chinese Universities,1994,15(5):763-766. |
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| Authors: | YUAN Jng ZHANG Wan-Jin NA Hui JI Xiang-Ling WANG Jun-Zuo Wu Zhong-Wen |
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| Abstract: | Poly(aryl ether ketones) are used as matrix resin in advanced high-performancecomposites because of their excellent properties. In this paper, diphenol-PEEKK has been prepared by copolycondensation of 4,4'-diphenol and 1,4-bis(p-fluorobenzoyl)benzene in the precence of diphenylsulphone. The general properties are studied by IR, DSC , TGA,etc.. The service temperature of diphenol-PEEKK is higher than that of PEEK, and the mechanical properties are as good as those of PEEK. The crystal structure of this polymer is also studied. |
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| Keywords: | Poly(ether ether ketone ketone) 4 4'-Diphenol 1 4-bis(p-fluorobenzoyl)benzene |
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