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| 氨基酸和羟肟酸混配的VO~(3+)配合物的IR、Raman和UV-Vis光谱研究 | |
| 引用本文： | 高山,郑瑜,刘世雄,段建平. 氨基酸和羟肟酸混配的VO~(3+)配合物的IR、Raman和UV-Vis光谱研究[J]. 光散射学报, 2000, 12(3): 125-128 |
| 作者姓名： | 高山 郑瑜 刘世雄 段建平 |
| 作者单位： | 1. 黑龙江大学化学化工学院,黑龙江,哈尔滨,150080 2. 中国科学院福建物质结构研究所,福建,福州,350002 3. 福州大学化学系,福建,福州,350002 |
| 摘 要： | 本文对四个钒酰配合物 [Vv O( L1- 3) ( bz) ]( H2 L1- 3分别为水杨醛缩合甘氨酸、缬氨酸、甲硫氨酸 ,Hbz为苯甲酰羟肟酸 )和 [Vv O( L4 ) ( bbz) ]( H2 L4 为水杨醛缩合丙氨酸 ,Hbbz为 N-苯基苯甲酰羟肟酸 )进行了 IR、Raman和 UV- Vis光谱研究。结果表明 ,在 IR和 Raman光谱中 ,它们有着相似的振动谱带 ,其νV=O特征振动频率出现在 962～ 976cm- 1之间 ;在 UV- Vis光谱中 ,含有 Hbz的配合物有两个配体场跃迁带 ,而含有 Hbbz的配合物只观测到一个配体场吸收带。 |
| 关 键 词： | VO~(3+)配合物 氨基酸配合物 羟肟酸配合物 谱学性质 |
| 文章编号： | 1004-5929(2000)03-0125-04 |
| 修稿时间： | 1999-04-22 |
Infrared, Raman, and UV-Vis Spectra of Oxovandium (V) Complexes Containing N-salicylideneamino Acids with Hydroxamate Ligands |
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| GAO Shan,ZHENG Yu,LIU Shi-xiong,DUAN Jian-ping. Infrared, Raman, and UV-Vis Spectra of Oxovandium (V) Complexes Containing N-salicylideneamino Acids with Hydroxamate Ligands[J]. Chinese Journal of Light Scattering, 2000, 12(3): 125-128 | |
| Authors: | GAO Shan ZHENG Yu LIU Shi-xiong DUAN Jian-ping |
| Abstract: | The IR, Raman, and UV Vis spectra of the complexes [V vO(L 1-3 )(bz)], where H 2L 1-3 is N salicylideneglycine, N salicylidene L valine, N salicylidene D, L methionine respectively, and Hbz is benzohydroxamic acid, and [V vO(L 4)(bbz)], where H 2L 4is N salicylidene L alanine and Hbbz is N phenyl benzoylhydroxamic acid, are studied. The results show that the complexes have similar absorption bands. Vibrational spectra indicate that the typical V=O stretching frequency appear in the range of 962 and 967 cm -1 . Two ligand field transitions are observed for the complexes with Hbz ligand, but only one ligandfield transition is present for the complex with Hbbz ligand in the absorption spectra. |
| Keywords: | VO 3+ complexes amino acid complexes hydroxamate complexes spectroscopic properties |
| 本文献已被 CNKI 维普 万方数据 等数据库收录！ | |