| 单磺化酞菁镓在水、微乳液中的解聚反应动力学研究 |
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| 引用本文： | 袁诗海,孙美丽,吴星.单磺化酞菁镓在水、微乳液中的解聚反应动力学研究[J].无机化学学报,1996,12(3):329-332. |
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| 作者姓名： | 袁诗海 孙美丽 吴星 |
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| 作者单位： | 扬州大学师范学院化学化工系 |
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| 基金项目： | 江苏省教委自然科学基金资助项目 |
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| 摘 要： | 本文研究了单磺化酞菁镓（ＳＰｃＧａ）在水、微乳液（ＴｒｉｔｏｎＸ－１００－壬烷－正戊醇－水）中的二聚现象和解聚反应动力学，测定了二聚平衡常数ＫＤ和解聚速率常数ｋ。结果表明：ＳＰｃＧａ的解聚反应速率与ＳＰｃＧａ的单体浓度ＣＭ和双体浓度ＣＤ的关系为：Ｖ＝ｋ１ＣＤ－ｋ２ＣＭ２
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| 关 键 词： | 酞菁，镓，微乳液 聚合，动力学 |
| 收稿时间： | 1995/9/19 0:00:00 |
STUDY ON THE AGGREGATION AND THE KINETICS OF AGGREGATION REACTION OF THE MONO-SULFOPHTHALOCYANINOATO GALLIUM IN THE AQUEOUS SOLUTION AND MICROEMULSION SYSTEM |
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| Yuan Shihai,Sun Meili and Wu Xing.STUDY ON THE AGGREGATION AND THE KINETICS OF AGGREGATION REACTION OF THE MONO-SULFOPHTHALOCYANINOATO GALLIUM IN THE AQUEOUS SOLUTION AND MICROEMULSION SYSTEM[J].Chinese Journal of Inorganic Chemistry,1996,12(3):329-332. |
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| Authors: | Yuan Shihai Sun Meili and Wu Xing |
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| Institution: | Department of Chemistry and Chemical Engineering, Yangzhou University, Yangzhou 225002,Department of Chemistry and Chemical Engineering, Yangzhou University, Yangzhou 225002 and Department of Chemistry and Chemical Engineering, Yangzhou University, Yangzhou 225002 |
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| Abstract: | The dimerization and kinetics of aggregation of mono-sulfophthal aninoato gallium (SPcGa) was studied in the aqueous solution and microemulsion system(Triton X-100-Pen-tanol-Monane-Water) by spectrophotometry.The dimerization constant(kDn) and the rate constant(k) of aggregation reaction of SPcGa were calculated. It shows that the rate of ag-gregation reaction of SPcGa can be expressed as follows:V=k1CD-k2CM2. Where Cm and CD are concentrations of monomer and dimer of SPcGa respectively. It also shows that kD of SPcGa is decreased in the microemulsion system as compared with that in aqueous solution. |
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| Keywords: | phthalocyanine gallium microemulsion aggregation kinetics |
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