| 双安息香缩乙二胺的合成及其配位性质 |
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| 引用本文： | 钟超凡,邓建成,童珏,朱文松,申桃江,谢超.双安息香缩乙二胺的合成及其配位性质[J].无机化学学报,1996,12(2):167-171. |
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| 作者姓名： | 钟超凡 邓建成 童珏 朱文松 申桃江 谢超 |
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| 作者单位： | 湘潭大学化学系，湘潭大学化学系，湘潭大学化学系，湘潭大学化学系，湘潭大学化学系，湘潭大学化学系 湘潭411105，湘潭411105，湘潭411105，湘潭411105，湘潭411105，湘潭411105，现在长春应用化学研究所 |
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| 摘 要： | 合成了双安息香缩乙二胺及其与 Ni( )、Pd( )、Pt( )、Zn( )、Cd( )和 Hg( )的配合物 ,并经质谱、红外光谱、元素分析和电子光谱等方法所表征 ;测定了溶液中配合物的稳定常数 ,并就该配体的特殊配位性质进行了讨论。
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| 关 键 词： | 双安息香缩乙二胺 合成 Ni(Ⅱ) Pd(Ⅱ)Pt() Zn(Ⅱ) Cd(Ⅱ) Hg(Ⅱ) |
| 收稿时间： | 1995/7/24 0:00:00 |
SYNTHESISAND COORDITATIVE PROPERTIES OF BIS-BENZOIN-SEMIETHYLENEDIAMINE |
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| Zhong Chaofan,Deng Jiancheng,Tong Jue,Zhu Wensong,Shen Taojiang and Xie Chao.SYNTHESISAND COORDITATIVE PROPERTIES OF BIS-BENZOIN-SEMIETHYLENEDIAMINE[J].Chinese Journal of Inorganic Chemistry,1996,12(2):167-171. |
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| Authors: | Zhong Chaofan Deng Jiancheng Tong Jue Zhu Wensong Shen Taojiang and Xie Chao |
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| Institution: | Departmentof Chemistry, Xiangtan University, Xiangtan 411105,Departmentof Chemistry, Xiangtan University, Xiangtan 411105,Departmentof Chemistry, Xiangtan University, Xiangtan 411105,Departmentof Chemistry, Xiangtan University, Xiangtan 411105,Departmentof Chemistry, Xiangtan University, Xiangtan 411105 and Departmentof Chemistry, Xiangtan University, Xiangtan 411105 |
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| Abstract: | Bis- benzion- semiethylenediamine was synthesized by condensation of benzoin with ethylenediamine and its complexes of Ni( ) ,Pd( ) ,Pt( ) ,Zn( ) ,Cd( ) and Hg( ) were synthesized.They were all characterized by elemental analysis,IR,MS and electronic spectra. The stability constantsof these complexesin DMSO- H2 O solution were determined and the special coordinating properties of this ligand was studied. The results showed that because the ligand is cavernous the stability of these complexes is related to radiusof metal ion. |
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