Base‐Stabilized Boryl and Cationic Haloborylene Complexes of Iron |
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| Authors: | Philipp Bissinger Prof Dr Holger Braunschweig Dr Alexander Damme Dr Rian D Dewhurst Dr Katharina Kraft Thomas Kramer Dr Krzysztof Radacki |
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| Institution: | Institut für Anorganische Chemie, Julius‐Maximilians‐Universit?t Würzburg, Am Hubland, 97074 Würzburg (Germany), Fax: (+49)?931‐31‐84623 |
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| Abstract: | The synthesis of base‐stabilized boryl and borylene complexes is reported. An N‐heterocyclic carbene (NHC)‐stabilized iron–dihydroboryl complex was prepared by two different routes including methane liberation and salt elimination. A range of base‐stabilized iron–dichloroboryl complexes was prepared by addition of Lewis bases to boryl complexes. Base‐stabilized, cationic monochloroborylene complexes were synthesized from these boryl complexes by halide abstraction by using weakly coordinating anions. |
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| Keywords: | boron boryl complexes borylene complexes carbenes iron |
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