Chiral Hypervalent Iodine Reagents: Synthesis and Reactivity |
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| Authors: | Dr. Alejandro Parra Dr. Silvia Reboredo |
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| Affiliation: | 1. Departamento de Química Orgánica (Módulo‐1), Facultad de Ciencias, Universidad Autónoma de Madrid, Cantoblanco, 28049 Madrid (Spain);2. Departamento de Química Orgánica I, Facultad de Ciencias Químicas, Universidad Complutense de Madrid, Ciudad Universitaria S/N, 28040 Madrid (Spain) |
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| Abstract: | ![]()
Chiral hypervalent iodine chemistry has been steadily increasing in importance in recent years. This review catalogues enantioselective transformations triggered by chiral hypervalent iodine(III/V) reagents, in stoichiometric or catalytic quantities, highlighting the different reactivities in terms of yield and enantioselectivity. Moreover, the synthesis of the most remarkable and successful catalysts has been illustrated in detail. |
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| Keywords: | asymmetric synthesis hypervalent iodine organocatalysis oxidation dearomatization |
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