Polymerization of o‐quinodimethanes. V. Ionic polymerization of o‐quinodimethanes generated by thermal isomerization of corresponding benzocyclobutenes |
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Authors: | Keisuke Chino Takeshi Endo |
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Institution: | Research Laboratory of Resources Utilization, Tokyo Institute of Technology, Nagatsuta‐cho 4259, Midoriku, Yokohama 226‐8501, Japan |
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Abstract: | The ionic polymerization of substituted o‐quinodimethanes via thermal isomerization of benzocyclobutenes is described. In the cationic polymerizations of 1‐methoxy‐o‐quinodimethane in the presence of various cationic initiators at 110 °C for 12 h, chain transfer reactions also considerably underwent besides the polymerization. Meanwhile, cationic polymerizations of 1‐trimethylsilyloxy‐o‐quinodimethane under the same conditions gave good yields of the corresponding polymer. Anionic polymerizations of 1‐cyano‐o‐quinodimethane in the presence of anionic initiators such as n‐BuLi or t‐BuOK were performed at various temperatures for 12 h. Good yields of hexane‐insoluble polymer, which was produced by anionic polymerization of corresponding o‐quinodimethane as an intermediate, were obtained above 120 °C. © 2007 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 46: 844–850, 2008 |
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Keywords: | anionic polymerization benzocyclobutene cationic polymerization isomerization o‐quinodimethane ring opening polymerization |
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