Zur Hydrolyse von 2,3‐Dihydro‐1,3‐di‐tert‐butyl‐4,5‐dimethylimidazol‐2‐yliden. Die Kristallstruktur von 1,3‐Di‐tert‐butyl‐4,5‐dimethylimidazoliumhydrogencarbonat |
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| Authors: | Ahmed Abu‐Rayyan Dr Qutaiba Abu‐Salem Norbert Kuhn Prof Dr Cäcilia Maichle‐Mößmer Manfred Steimann Gerald Henkel |
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| Institution: | 1. Faculty of Pharmacy, Al Isra University, P.O. Box 22 and 33, Al Isra University Post Office, 11622 Jordan;2. Tübingen, Institut für Anorganische Chemie der Universit?t;3. Paderborn, Fachbereich Chemie der Universit?t |
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| Abstract: | On the Hydrolysis of 2,3‐Dihydro‐1,3‐di‐tert‐butyl‐4,5‐dimethylimidazol‐2‐ylidene. The Crystal Structure of 1,3‐Di‐tert‐butyl‐4,5‐dimethylimidazolium Bicarbonate 1,3‐Di‐tert‐butyl‐4,5‐dimethylimidazolium bicarbonate ( 7 ), formed on the exposure of 2,3‐dihydro‐1,3‐di‐tert‐butyl‐4,5‐dimethylimidazol‐2‐ylidene ( 6 ) towards air, is prepared on the reaction of 6 with ammonium bicarbonate; its crystal structure analysis reveals the presence of dimeric bicarbonate anions linked to each other and to the imidazolium ions with hydrogen bonds. |
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| Keywords: | Carbenes Carbonates Hydrogen bonds Crystal structures |
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