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Layer‐by‐layer assembly of gelatin
Authors:Yuan Lin  Zhaohui Su
Affiliation:1. State Key Laboratory of Polymer Physics and Chemistry, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun, Jilin 130022, China;2. Department of Materials Science and Engineering, Jilin University, Changchun 130025, China
Abstract:Electrostatic assembly of one species can be realized using gelatin as a polyampholyte. Under suitable conditions where the electrostatic attraction and repulsion were both significant and in balance, linear growth of multilayers driven by electrostatic interactions was sustained over many successive assembly steps, and the maximum amount of adsorption of each layer was reached when the solution pH was around the isoelectric point. The rearrangement of the adsorbed chains after drying was confirmed by contact angle analysis. In addition with only one species involved, the assembled thin films should be chemically uniform rather than layered. © 2008 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 46: 1252–1257, 2008
Keywords:gelatin  layer growth  polyampholyte  self‐assembly  thin films
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