高氯酸二水邻菲咯啉合铜配合物的合成和晶体结构

Crystal structure of the title compound， Cu(phen)(H₂O)₂·ClO₄(phen=1，10-phenanthroline)， was deter-mined by X-ray crystallography. It crystallizes in the monoclinic system， space group C2/c with lattice parameters a=1.49071(4)nm， b=1.38594(4)nm， c=0.70292(1)nm， β=108.509(1)° and Z=4; The Cu(Ⅰ) ion is chelated by a phen ligand and two aqua ligands in cis arrangement and assumes a C2 symmetric square-planar geometry with the CuN₂O₂ core. Eight Cu(phen)(H₂O)₂·ClO₄ molecules are interconnected by strong hydrogen bonds between coordinated water molecules and uncoordinated perchlorate anions to form a molecular scale cavities along c axis. The bond distances of Cu-N and Cu-O are 0.2003(4)nm and 0.1973(3)nm， respectively. CCDC： 197600.

Synthesis and Crystal Structure of Cu (phen) (H2O)2·ClO4 (phen = phenanthroline)

Crystal structure of the title compound, Cu(phen) (H2O) 2 @ C1O4(phen = 1, 1O-phenanthroline), was deter-mined by X-ray crystallography. It crystallizes in the monoclinic system, space group C2/c with lattice parametersa = 1. 49071 (4) nm, b = 1. 38594(4) nm, c = 0. 70292(1) nm, β = 108. 509(1) ° and Z = 4; The Cu (Ⅰ) ion ischelated by a phen ligand and two aqua ligands in cis arrangement and assumes a C2 symmetric square-planargeometry with the CuN2O2 core. Eight Cu(phen)(H2O)2 @ ClO4 molecules are interconnected by strong hydrogenbonds between coordinated water molecules and uncoordinated perchlorate anions to form a molecular scale cavitiesalong c axis. The bond distances of Cu-N and Cu-O are 0. 2003(4) nm and 0. 1973(3) nm, respectively. CCDC:197600.