The thermodynamic properties of magnesium uranoborate tetrahydrate |
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Authors: | N G Chernorukov N N Smirnova A V Knyazev M N Marochkina A V Ershova |
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Institution: | (1) Nizhni Novgorod State University, pr. Gagarina 23, Nizhni Novgorod, 603950, Russia |
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Abstract: | The standard enthalpy of formation of crystalline Mg(BUO5)2 · 4H2O at 298.15 K (?5563 ± 10 kJ/mol) was determined by reaction calorimetry. The heat capacity of the compound was studied over the temperature range 8–340 K by adiabatic vacuum calorimetry, and its thermodynamic functions were calculated. The standard entropy and Gibbs function of formation at 298.15 K (?1692.2 ± 3.4 J/(mol K) and ?5059 ± 11 kJ/mol, respectively) were determined. |
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