| 金(Ⅲ)与杯[4]乙酯合钠髣超分子化合物:[Na(C_(60)H_(80)O_(12))]~ [Au(SCN)_4]~-的合成、结构及性能 |
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| 引用本文： | 付勇,徐琰,宋毛平,吴养洁.金(Ⅲ)与杯[4]乙酯合钠髣超分子化合物:[Na(C_(60)H_(80)O_(12))]~ [Au(SCN)_4]~-的合成、结构及性能[J].无机化学学报,2005(3). |
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| 作者姓名： | 付勇 徐琰 宋毛平 吴养洁 |
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| 作者单位： | 郑州大学化学系 郑州450052
(付勇，徐琰，宋毛平)，郑州大学化学系 郑州450052(吴养洁) |
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| 基金项目： | 国家自然科学基金资助项目(No.20171040)，郑州大学青年骨干教师基金资助项目 |
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| 摘 要： | 0引言杯芳烃是由酚环和亚甲基组成的环多聚体,杯芳烃奇异的环状结构和可调节的空穴特征,引起广大化学工作者的浓厚研究兴趣,不同类型的新型杯芳烃及其衍生物已相继被合成出来1]。其中有些杯芳烃化合物在浓缩分离、催化仿生、环境保护等方面已显示出良好的应用性能2,3];一些杯
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| 关 键 词： | 杯[4]芳烃 金髥 超分子化合物 合成 晶体结构 |
Synthesis,Crystal Structure and Characterization ofa Novel Super Molecule [Na(C_(60)H_(80)O_(12))]~ [Au(SCN)_4]~- |
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| FU Yong XU Yan SONG Mao-Ping WU Yang-Jie.Synthesis,Crystal Structure and Characterization ofa Novel Super Molecule [Na(C_(60)H_(80)O_(12))]~ [Au(SCN)_4]~-[J].Chinese Journal of Inorganic Chemistry,2005(3). |
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| Authors: | FU Yong XU Yan SONG Mao-Ping WU Yang-Jie |
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| Institution: | FU Yong XU Yan SONG Mao-Ping* WU Yang-Jie* |
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| Abstract: | A novel super molecule Na(C60H80O12)] - was obtained by ext raction of calix arene (L) for an aqueous solution containing -, and N aCl into CH2Cl2. The crystal structure and properties of the title super molecul e were characterized by single-crystal X-ray diffraction, IR and 1H NMR spectra. The X-ray single crystal structure analysis shows that the crystal was Tetragon al system with space group P4/n and the unit cell parameters were as follows: a= 2.880 8(18) nm, b=2.880 8(18) nm, c=2.292 4(5) nm, and final R indices : R1=0.048 5, wR2=0.106 1. CCDC: 243229. |
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| Keywords: | calixarene gold(III) association complex synthesis crystal str ucture |
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