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WATER STATES IN SBR BASED WATER SWELLING RUBBER
作者姓名:张书香  李效玉  陈勇  夏宇正  焦书科
作者单位:The Applied Chemistry Department,Shandong Institute of Building Materials,Shandong 250022,China,The Institute of Material Science and Engineering,Beijing University of Chemical Technology,Beijing 100029,China,The Institute of Material Science and Engineering,Beijing University of Chemical Technology,Beijing 100029,China,The Institute of Material Science and Engineering,Beijing University of Chemical Technology,Beijing 100029,China,The Institute of Material Science and Engineering,Beijing University of Chemical Technology,Beijing 100029,China
基金项目:Project supported by the National Natural Science Foundation of China.
摘    要:Water swelling rubber (WSR) was prepared by reaction blending SBR andsodium polyacrylate (PAANa). The existing states of water in the WSR was studied bymeans of DSC and TG. It was found that water exists in three states: nonfreezing water,bound freezable water and free water. The relationships between water states and structureof PAANa were investigated. The results showed that the amount of non-freezing waterwas related to total water content, and the ratio of non-freezing water versus -COONagroups on PAANa (mol/mol) was about 4. However, total water content slightly affectedthe content of bound freezable water and remarkably affected the amount of free waer.

收稿时间:1998-03-13

WATER STATES IN SBR BASED WATER SWELLING RUBBER
ZHANG Shuxiang,LI Xiaoyu,CHEN Yong,XIA Yuzheng,JIAO Shuke.WATER STATES IN SBR BASED WATER SWELLING RUBBER[J].Chinese Journal of Polymer Science,1998,0(4):345-350.
Authors:ZHANG Shuxiang  LI Xiaoyu  CHEN Yong  XIA Yuzheng  JIAO Shuke
Institution:The Applied Chemistry Department; Shandong Institute of Building Materials; Shandong 250022; China The Institute of Material Science and Engineering; Beijing University of Chemical Technology; Beijing 100029; China
Abstract:Water swelling rubber (WSR) was prepared by reaction blending SBR andsodium polyacrylate (PAANa). The existing states of water in the WSR was studied bymeans of DSC and TG. It was found that water exists in three states: nonfreezing water,bound freezable water and free water. The relationships between water states and structureof PAANa were investigated. The results showed that the amount of non-freezing waterwas related to total water content, and the ratio of non-freezing water versus -COONagroups on PAANa (mol/mol) was about 4. However, total water content slightly affectedthe content of bound freezable water and remarkably affected the amount of free waer.
Keywords:Water swelling rubber  Water states  DSC
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