Structuring of polyacrylonitrile solutions |
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| Authors: | I G Silinskaya A V Novoselova Yu N Sazanov A V Gribanov I N Serov V I Margolin |
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| Institution: | (1) Institute of Macromolecular Compounds, Russian Academy of Sciences, St. Petersburg, Russia;(2) AIRES Foundation for Development of New Medical Technologies, St. Petersburg, Russia |
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| Abstract: | Mechanisms of orientation for the solutions of polyacrylonitrile synthesized under conditions of radical and anionic polymerization were studied. The effect of the fractal-matrix structuring agent developed by the AIRES foundation on the correlation parameters of the solution density and average squared fluctuation polarizability, which can be used to determine how the supramolecular structure changes by “self-orientation” and “induced orientation” mechanisms, was analyzed. |
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