Platinum-mercury compounds as intermediates to mono- and di-arylplatinum(II) complexes |
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Authors: | O. Rossell J. Sales M. Seco |
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Affiliation: | Departament de Química Inorgànica, Facultat de Química, Universitat de Barcelona, Diagonal 647, Barcelona (28) Spain |
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Abstract: | The reaction of HgR2 (R = 2,5-C6H3Cl2; 2,3,4- and 2,4,6-C6H2Cl3; 2,3,4,5-,2,3,4,6- and 2,3,5,6-C6HCl4 and C6Cl5) with Pt(PPh3)3 gives the new stable compounds [(PPh3)2RPt(HgR)] containing PtHg bonds. When R contains an ortho chlorine atom (R = 2,5-C6H3Cl2; 2,3,4-C6H2Cl3 and 2,3,4,5-C6HCl4) refluxing xylene solutions of these compounds gives the complexes [PtR2-(PPh3)2], with simultaneous precipitation of mercury. In the other cases the initial compounds are recovered unaltered. All the compounds containing the PtHg bond react readily with CF3COOH to give a new series of compounds of formula [Pt(O2CCF3)R(PPh3)2]. |
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