Free radical reactions in solution : VIII. Radical-initiated addition of trialkylsilanes across alkene CC bonds |
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Authors: | Nabil MK El-Durini Richard A Jackson |
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Institution: | School of Chemistry and Molecular Sciences, University of Sussex, Brighton BN1 9QJ Great Britain |
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Abstract: | Difficulties in carrying out the free-radical addition of trialkylsilanes (as opposed to trichlorosilane) to alkene CC bonds are partly due to telomerization competing with the radical transfer step. This can be overcome by the use of a large excess of trialkylsilane, when good yields of adduct are obtained from mono-substituted and 1,2-disubstituted alkenes. |
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