Interaction of pyridineplatinum(II) complexes with alkyl sulfoxides |
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Authors: | D. A. de Vekki |
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Affiliation: | (1) St. Petersburg State Technological Institute (Technical University), Moskovskii pr. 26, St. Petersburg, 198013, Russia |
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Abstract: | Interaction of pyridineplatinum(II) complexes with dimethyl sulfoxide and diethyl sulfoxide is studied by NMR spectroscopy. The interaction products are pyridinesulfoxide and bissulfoxide platinum(II) complexes. Cis-trans isomerization of the products is observed along with the substitution reaction and determines the final configuration of the complexes. |
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