Diastereoselective cobalt-catalyzed reductive aldol cyclizations using diethylzinc as the stoichiometric reductant |
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| Authors: | Lam Hon Wai Joensuu Pekka M Murray Gordon J Fordyce Euan A F Prieto Oscar Luebbers Thomas |
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| Affiliation: | School of Chemistry, University of Edinburgh, The King's Buildings, West Mains Road, Edinburgh, EH9 3JJ, United Kingdom. h.lam@ed.ac.uk |
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| Abstract: | ![]()
[reaction: see text] Cobalt catalysis enables a new method for the generation of zinc enolates using diethylzinc to reduce alpha,beta-unsaturated amides. This method has been applied to a high-yielding diastereoselective reductive aldol cyclization. |
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