Synthesis and optical and electrochemical properties of glucose-cored ferrocenyl dendrimers |
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| Authors: | Ayyavoo Kannan Ramasamy Anandhan |
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| Affiliation: | 1. Department of Organic Chemistry, University of Madras, Chennai, India;2. Department of Chemistry, University of the Free State, Bloemfontein, South Africa |
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| Abstract: | Triazole-based ferrocenyl glycoconjugates 1, 2, and 3 were synthesized by regiospecific copper(I)-catalyzed azide–alkyne cycloaddition (CuAAC) of azidoferrocenyl derivatives with glucose pentaacetylide. Higher generation ferrocenyl glycoconjugates form the stable ferrocenium cation and exhibit increased light harvesting property as revealed from cyclic voltammogram studies and ultraviolet–visible spectrum respectively due to the presence of more ferrocenyl and triazolyl units than the lower generation dendrimer. |
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| Keywords: | Click chemistry cyclic voltammogram dendrimer ferrocene glucose |
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