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Facile synthetic route to benzo[c]chromenones and thieno[2,3-c]chromenones
Authors:Olga Ya Shyyka  Roman L Martyak  Mykola A Tupychak  Nazariy T Pokhodylo  Mykola D Obushak
Institution:1. Department of Organic Chemistry, Ivan Franko National University of Lviv, Lviv, Ukraineshiyka.olya@gmail.com;3. Department of Organic Chemistry, Ivan Franko National University of Lviv, Lviv, Ukraine
Abstract:Convenient two-step procedure for the synthesis of fused chromenone derivatives was developed. Reduction of the obtained in the Meerwein arylation reaction aryl- and thienylquinones allowed to construct 6H-benzoc]chromene-6-ones and 4H-thieno2,3-c]chromen-4-one in a more cost- and time-effective manner in comparison with already known methods. The obtained products have provided a new entry to chromenone derivatives.
Keywords:6H-Benzo[c]chromene-6-ones  4H-thieno[2  3-c]chromen-4-one  diazonium salts  Meerwein arylation reaction  quinone
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