| 烯烃不对称双羟化及其反应机理的研究进展 |
| |
| 引用本文： | 杜锦发,高志玲.烯烃不对称双羟化及其反应机理的研究进展[J].有机化学,1992,12(6):561-566. |
| |
| 作者姓名： | 杜锦发 高志玲 |
| |
| 作者单位： | 广东省药物研究所，广东省药物研究所 广东，广州，510180，广东，广州，510180 |
| |
| 摘 要： | 本文综述了近年来四氧化锇催化烯烃不对称双羟化及其反应机理的研究进展。Sharpless等对烯烃双羟化机理的透彻研究导致了不对称双羟化方法的优化。
|
| 关 键 词： | 催化 反应机理 烯烃 奎宁 羟基化 四氧化锇 奎尼定 |
Recent progress in the asymmetric dihydroxylation and the dihydroxylating mechanism of olefins |
| |
| DU Jin-Fa,GAO Zhi-Ling Guangdong Institute of Materia Medica, Guangzhou,Guangdong.Recent progress in the asymmetric dihydroxylation and the dihydroxylating mechanism of olefins[J].Chinese Journal of Organic Chemistry,1992,12(6):561-566. |
| |
| Authors: | DU Jin-Fa GAO Zhi-Ling Guangdong Institute of Materia Medica Guangzhou Guangdong |
| |
| Institution: | DU Jin-Fa,GAO Zhi-Ling Guangdong Institute of Materia Medica,510180 Guangzhou,Guangdong |
| |
| Abstract: | This paper reviews briefly the recent progress in the investigation on the asym-
metric dihydroxylation and the dihydroxylating mechanism of olefins. A mechanistic insight
leads to a greatly improved osmium-catalized asymmetric dihydroxylation process. |
| |
| Keywords: | asymmetric dihdroxylation reaction mechanism dihyroxylation osmium tetroxide quinine quinidine olefin catalysis |
| 本文献已被 CNKI 维普 等数据库收录！ |
| 点击此处可从《有机化学》浏览原始摘要信息 |
| 点击此处可从《有机化学》下载免费的PDF全文 |
