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| Synthesis and Crystal Structure of Bi（2-nitrilethyl）aminoacetonitrile | |
| 引用本文： | 高键,许兴友,程青芳,杨绪杰,陆路德,汪信,李一志,刘永江. Synthesis and Crystal Structure of Bi（2-nitrilethyl）aminoacetonitrile[J]. 结构化学, 2004, 23(4): 413-416 |
| 作者姓名： | 高键 许兴友 程青芳 杨绪杰 陆路德 汪信 李一志 刘永江 |
| 作者单位： | GAO Jiana XU Xing-Youa，b CHENG Qing-Fangb YANG Xu-Jie a LU Lu-Dea② WANG Xin a LI Yi-Zhic LIU Yong-Jiangc a (Materials Chemistry Laboratory，Nanjing University of Science & Technology，Nanjing 210094，China) b (Department of Chemical Engineering，Huaihai Institute of Technology，Lianyungang 222005，China) c (State Key Laboratory of Coordination，Coordination Chemistry Institute，Nanjing University，Nanjing 210093，China) |
| 基金项目： | theFoundationofScienceCommitteeofJiangsuprovince(No.BK2002100)，theFoundationofScienceCommitteeofLianyungangcity(GY200303) |
| 摘 要： | 1INTRODUCTIONTheresearchonorganicpolyaminesiscur-rentlyofgreatinterestbecauseoftheirpotentialapplicationsasusefulorganicligands,inwhichtheaminenitrogenatomshavestrongcoordinationabilitytothetransitionmetalions.Theirtransitionmetalcomplexesplayanexcellentr… |
| 关 键 词： | 合成 晶体结构 二（2-腈乙基）氨基乙腈 不等边结构 |
Synthesis and Crystal Structure of Bi(2-nitrilethyl)aminoacetonitrile |
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| Affiliation: | Materials chemistry Laboratory,Nanjing University of Science&Technology,Nanjing 210094,China;Materials chemistry Laboratory,Nanjing University of Science&Technology,Nanjing 210094,China;Department of Chemical Engineering,Huaihai Institute of Technology,Lianyungang 222005,China;Department of Chemical Engineering,Huaihai Institute of Technology,Lianyungang 222005,China;State Key Laboratory of Coordination,Coordination Chemistry Institute,China |
| Abstract: | The title compound bi(2-nitrilethyl)aminoacetonitrile has been prepared by the addition reaction of aminoacetonitrile with acrylonitrile, and its crystal structure was determined by single-crystal X-ray diffraction. The compound (C8H10N4) crystallizes in monoclinic, space group P21/n with a = 7.646(12), b = 14.578(2), c = 8.341(1) ? ?= 100.38(1)? V = 914.5(14) 3, Mr = 162.20, Z = 4, F(000) = 344, Dc = 1.178 g/cm3, T = 293 K, = 0. 077 mm-1 and l = 0.71073 ? The structure was refined to R = 0.0574 and wR = 0.1331 for 1107 observed reflections with I > 2(I). |
| Keywords: | bi(2-nitrilethyl)aminoacetonitrile synthesis crystal structure inequilateral structure |
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