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A novel chiral terpyridine macrocycle as a fluorescent sensor for enantioselective recognition of amino acid derivatives |
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| Authors: | Wong Wing-Leung Huang Ka-Hung Teng Pang-Fei Lee Chi-Sing Kwong Hoi-Lun |
| Affiliation: | Department of Biology and Chemistry, Open Laboratory of Chirotechnology, Institute of Molecular Technology for Drugs Discovery and Synthesis, City University of Hong Kong, 83 Tat Chee Avenue, Kowloon Tong, Hong Kong SAR, China. |
| Abstract: | Terpyridine macrocycle 1 is shown to be a strong chelating agent for organic ammonium salts and also a useful chromophore in fluorescent sensing. It exhibits very good enantioselectivity (K(obs)(S)/K(obs)(R)= 3.8) in chiral discrimination of alpha-phenylglycine methyl ester hydrochloride (PhEtOMe). |
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