Complex Compounds of Azomethines with an MN2S2 Five-membered Coordination Unit: Metal Chelates of 2-{[4-(3,5-Diphenyl-4,5-dihydropyrazol-1-yl)benzylidene]amino}benzenethiol |
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| Authors: | Burlov A S Borodkina I G Kuznetsova L I Uraev A I Makarova N I Vasil'chenko I S Borodkin G S Altun O Feiizoglu A Garnovskii A D |
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| Institution: | (1) Rostov State University, Rostov-on-Don, Russia;(2) Turkey |
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| Abstract: | Chelate complexes of 2-{4-(3,5-diphenyl-4,5-dihydropyrazol-1-yl)benzylidene]amino}benzenethiol (LH) of the ML2 composition and with an M2N2S2 five-membered coordination unit were obtained. The syntheses were carried out by chemical (from LH and metal acetates) and electrochemical (from LH and zerovalent metals) methods in methanol. The chelate compounds were assigned cis-planar (M = Ni) and tetrahedral (M = Co, Zn, Cd) configurations. |
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