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Highly efficient removal of Cr(VI) from wastewater via adsorption with novel magnetic Fe3O4@C@MgAl-layered double-hydroxide
Authors:Hui Zhang  Fei Huang  De-Lei Liu  Peng Shi
Institution:1.College of Chemistry and Chemical Engineering, Southwest Petroleum University, Chengdu 610500, China;2.Oil & Gas Field Applied Chemistry Key Laboratory of Sichuan Province, Southwest Petroleum University, Chengdu 610500, China;3.Xinjiang Petroleum Survey and Design Institute, Urumqi 830026, China
Abstract:Novel magnetic Fe3O4@C@MgAl-layered double-hydroxide (LDH) nanoparticles have been successfully prepared by the chemical self-assembly methods. The properties of surface functional groups, crystal structure, magnetism and surface morphology of magnetic nanoparticles were characterized by Fourier transform infrared spectroscopy (FT-IR), X-ray diffraction (XRD), thermal gravity-differential thermal gravity (TG-DTG), scanning electron microscopy (SEM), and transmission electron microscopy (TEM). The adsorption studies of the novel adsorbent in removing heavy metals Cr (VI) from waste water showed that the maximum absorption amount of Cr(VI) was 152.0 mg/g at 40℃ and pH 6.0. The excellent adsorption capacity of the Fe3O4@C@MgAl-LDH nano-absorbents plus their easy separation, environmentally friendly composition and reusability makes them more suitable adsorbents for the removal of metal ions from waste water.
Keywords:Magnetic nanoparticles  MgAl-layered double-hydroxide  Adsorption  Chromium(VI)  
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