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Facile synthesis of 1-naphthols through a copper-catalyzed arylation of methyl ketones with o-bromoacetophenones |
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| Authors: | Zhen-Bang Lou Xin-Long Pang Chao Chen Li-Rong Wen Ming Li |
| Affiliation: | 1.College of Chemistry and Molecular Engineering, Qingdao University of Science and Technology, Qingdao 266042, China;2.Key Laboratory of Bioorganic Phosphorus Chemistry & Chemical Biology(Ministry of Education), Department of Chemistry, Tsinghua University, Beijing 100084, China |
| Abstract: | The coupling reactions of simple methyl ketones with o-bromoacetophenones and subsquential cyclization reactions were realized to produce a range of 1-naphthols. These cascade reactions were initiated by a rare Cu-catalyzed arylation reaction of methyl ketones with aromatic bromides. |
| Keywords: | Copper Arylation Ketones Naphthol |
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