| Zinc(Ⅱ) coordination architectures based on 5-(1H-tetrazol-1-yl)-isophthalic acid:Synthesis,structures and luminescent properties |
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| 引用本文： | Shu-Ming Zhang,Gui-Xiang Wang,Peng Guo,Yu-Huan Chen. Zinc(Ⅱ) coordination architectures based on 5-(1H-tetrazol-1-yl)-isophthalic acid:Synthesis,structures and luminescent properties[J]. 中国化学快报, 2015, 26(9): 1079-1084. DOI: 10.1016/j.cclet.2015.05.025 |
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| 作者姓名： | Shu-Ming Zhang Gui-Xiang Wang Peng Guo Yu-Huan Chen |
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| 作者单位： | School of Chemical Engineering and Technology, Hebei University of Technology, Tianjin 300130, China |
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| 基金项目： | This work is supported by the Natural Science Foundation of Hebei Province (No. B2012202019) and the National Natural Science Foundation of China (No. 21206027). |
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| 摘 要： | With different pyridine-analogs as auxiliary ligands,three novel Zn(Ⅱ) complexes(1-3) based on 5-(1Htetrazol-1-yl) isophthalic acid(H_2L) have been synthesized and structurally characterized.Single crystal X-ray diffraction analyses of complexes 1-3 show the presence of tetrazolyl group,as well as the coordination behavior of the auxiliary ligands as critical factors determining the structures of such Zn(Ⅱ)-carboxyIate coordination architectures.In addition,the resulting complexes all exhibit luminescence properties in the solid state at room temperature.
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Zinc(II) coordination architectures based on 5-(1H-tetrazol-1-yl)-isophthalic acid: Synthesis,structures and luminescent properties |
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| Shu-Ming Zhang,Gui-Xiang Wang,Peng Guo,Yu-Huan Chen. Zinc(II) coordination architectures based on 5-(1H-tetrazol-1-yl)-isophthalic acid: Synthesis,structures and luminescent properties[J]. Chinese Chemical Letters, 2015, 26(9): 1079-1084. DOI: 10.1016/j.cclet.2015.05.025 |
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| Authors: | Shu-Ming Zhang Gui-Xiang Wang Peng Guo Yu-Huan Chen |
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| Affiliation: | School of Chemical Engineering and Technology, Hebei University of Technology, Tianjin 300130, China |
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| Abstract: | With different pyridine-analogs as auxiliary ligands, three novel Zn(II) complexes (1-3) based on 5-(1H-tetrazol-1-yl) isophthalic acid (H2L) have been synthesized and structurally characterized. Single crystal X-ray diffraction analyses of complexes 1-3 show the presence of tetrazolyl group, as well as the coordination behavior of the auxiliary ligands as critical factors determining the structures of such Zn(II)-carboxylate coordination architectures. In addition, the resulting complexes all exhibit luminescence properties in the solid state at room temperature. |
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| Keywords: | Zn(II)-carboxylate complex Pyridine-analogs Structure-tuning Luminescent properties |
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