| 甲苯-乙醇介质中二茂铁催化分解过氧化氢机理的探讨 |
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| 引用本文： | 郁章玉,齐丽云,秦梅,郭道军,王慧云.甲苯-乙醇介质中二茂铁催化分解过氧化氢机理的探讨[J].应用化学,2004,21(1):41-0. |
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| 作者姓名： | 郁章玉 齐丽云 秦梅 郭道军 王慧云 |
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| 作者单位： | 曲阜师范大学，中国科学院化学研究所，中科院化学研究所，石油大学(北京)化工学院 |
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| 基金项目： | 国家自然科学基金 (2 9673 0 2 5 )，山东省自然科学基金 (Y2 0 0 0B0 3 )资助项目 |
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| 摘 要： | 甲苯-乙醇介质中二茂铁催化分解过氧化氢机理的探讨;电子转移机理
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| 关 键 词： | 甲苯-乙醇介质中二茂铁催化分解过氧化氢机理的探讨 电子转移机理 |
| 文章编号： | 1000-0518(2004)01-0041-04 |
| 收稿时间： | 2009-06-29 |
| 修稿时间： | 2003年3月25日 |
Decomposition Mechanism of Hydrogen Peroxide Catalyzed by Ferrocene in Toluene-Ethanol Mixed Solution |
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| YU Zhang-Yu a ,QI Li-Yun a,b,QIN Mei a,GUO Dao-Jun a,WANG Hui-Yun c.Decomposition Mechanism of Hydrogen Peroxide Catalyzed by Ferrocene in Toluene-Ethanol Mixed Solution[J].Chinese Journal of Applied Chemistry,2004,21(1):41-0. |
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| Authors: | YU Zhang-Yu a QI Li-Yun a b QIN Mei a GUO Dao-Jun a WANG Hui-Yun c |
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| Institution: | YU Zhang-Yu a *,QI Li-Yun a,b,QIN Mei a,GUO Dao-Jun a,WANG Hui-Yun c |
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| Abstract: | The electrochemical behavior of ferrocene in the absence and presence of hydrogen peroxide in toluene-ethanol mixed solutions were investigated at a platinum electrode by cyclic voltammetry and AC impedance measurements. The results show that increasing toluene in the solution mixture leads to increase of both solution resistance and electrochemical reaction resistance of ferrocene at the Pt electrode. Ferricinium ion could react with hydrogen peroxide in the liquid phase. The electrode process is considered to be followed by catalytic EC(electron transfer-chemical reaction) mechanism. |
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| Keywords: | toluene-ethanol mixture ferrocene hydrogen peroxide electron transfer mechanism |
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