| 几种叔丁墓酚化合物的核磁共振研究 |
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| 引用本文： | 陈星彩,刘宁.几种叔丁墓酚化合物的核磁共振研究[J].波谱学杂志,1989,6(4):501-508. |
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| 作者姓名： | 陈星彩 刘宁 |
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| 作者单位： | 1. 北京石油勘探开发科学研究院;2. 广州石油化学总厂 |
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| 摘 要： | 研究了11种叔丁基酚化合物的化学位移和偶合常数,并讨论了影响因素.
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| 关 键 词： | 1H 13C核磁共振 叔丁基酚化合物 化学位移 偶合常数 |
| 收稿时间： | 1987-10-10 |
NMR STUDY OF TERT-BUTYL PHENOL COMPOUNDS |
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| Chen Xingcai,Liu Ning.NMR STUDY OF TERT-BUTYL PHENOL COMPOUNDS[J].Chinese Journal of Magnetic Resonance,1989,6(4):501-508. |
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| Authors: | Chen Xingcai Liu Ning |
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| Institution: | 1. Research Institute of Petroleum Exploration and Development, Beijing;2. Guangzhou Petro-Chemical works |
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| Abstract: | 1H and 13C chemical shifts of tert-butyl phenol compounds were determined by NMR. 13C-1H one bond and long-range coupling constants (nJCOH). 13C-1H gcminal coupling constants over the C-OH chain (2JCOH) and 13C-31P coupling constants (nJCP) in It tert-butyl phenol compounds were obtained.The coupling constants between aromatic hydrogen and aromatic carbon and the coupling constants between aromatic hydrogen (carbon) and aliphatic carbon (hydrogen) directly attached to aromatic are discussed. Induced and stcric effects on the coupling constants are also discussed. |
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| Keywords: | Tert-butyl phenol compounds 1H & 13C NMR Chemical shift Coupling constant |
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