Diazo reactions with unsaturated compounds: XI. Reactions of benzene-, p-methylbenzene-, and p-methoxybenzenesulfonyl-1,3-butadienes with arenediazonium chlorides and 1-aryl-3,3-dimethyl-1-triazenes |
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Authors: | V V Smalius V M Naidan |
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Institution: | (1) Khmel’nitskii National University, bulv. Shevchenko 81, Cherkassy, 18031, Ukraine |
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Abstract: | 1-(p-Methylbenzene)-and 1-(p-methoxybenzenesulfonyl)-1,3-butadienes in aqueous acetone in the presence of copper(I) or copper(II) chlorides react with arenediazonium chlorides and 1-aryl-3,3-dimethyl-1-triazenes to form 1-(p-methylbenzene)-and 1-(p-methoxybenzenesulfonyl)-4-aryl-3-chloro-1-butenes, respectively. 1-(Benzenesulfonyl)-1,3-butadiene undergoes tarring under the same conditions. |
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